By Arthur Adamson (Auth.)

ISBN-10: 0120442604

ISBN-13: 9780120442607

ISBN-10: 0120442620

ISBN-13: 9780120442621

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Extra resources for A Textbook of Physical Chemistry

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2-28) now requires a three-dimensional plot for its display, as illustrated in Fig. 2-2. Again the maximum is at u and ν equal to zero, and, of course, it is symmetric with respect to positive and negative velocities. It is ordinarily of more interest to deal with the net velocity c than with the separate components. That is, although the u and ν velocity components represent 2 independent ways in which the molecule can have kinetic energy, it is the net velocity of the molecule and its total kinetic energy mc /2 that are needed for most applications.

2-4 Average Quantities from the Distribution Laws It is a common experience to take the average of some property for a collection of objects. For example, the average value of a coin in a bag of mixed coins would be obtained by dividing the total value by the number of coins. In more detail, the operation is one of dividing two sums: (2-34) That is, the product of the value s{ of the ith type of coin times the number Ni of such coins is summed over all types and is then divided by Σ N{, the total number of coins.

GLASSTONE, S. (1946). " Van Nostrand-Reinhold, Princeton, New Jersey. HIRSCHFELDER, J. , CURTISS, C. , AND BIRD, R. B . (1964). "Molecular Theory of Gases and Liquids," corrected ed. Wiley, New York. MACDOUGALL, F. H . (1936). / . Amer. Chem. Soc. 5 8 , 2585. WESTON, F. (1950). "An Introduction to Thermodynamics. " Addison-Wesley, Reading, Massachusetts. EXERCISES AND PROBLEMS As noted in the Preface, each section of this type is divided into three parts. The first consists of Exercises, or very straightforward illustrations of the textual material.

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A Textbook of Physical Chemistry by Arthur Adamson (Auth.)


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